WebFor the preparation of MOFs which can be modified via postsynthetic modification, a homologous series of p-terphenyl-4,4′-dicarboxylic acid having hydroxyl side groups, ranging from 0 to 4, as functional groups have been synthesized. Then the modified IRMOF-16, named as HCC-1, has been successfully synthesized via solvothermal and microwave … WebDeepDyve is the largest online rental service for scholarly research with thousands of academic publications available at your fingertips.
Postsynthetic Modification: An Enabling Technology for the …
WebNov 23, 2016 · Functionalization has been shown to have a marked effect on the properties of an MOF. For example, Deng et al.() synthesized an MOF-5 variant with three different functional groups and found it to have a 400% increase in selectivity for CO 2 over CO when compared to the unfunctionalized parent MOFUsing density functional theory to guide … WebNov 27, 2016 · In solvothermal synthesis of MOFs, sensitive functional groups do not survive under harsh reaction conditions, thus limiting the scope of functional groups that can be incorporated into the MOF. Instead, these sensitive functional groups can be incorporated into MOFs via postsynthetic modifications under relatively mild conditions … mass gas fireplace repair
Functionalization of Metal–Organic Frameworks through the …
WebJan 2, 2024 · Metal-organic frameworks (MOFs) are a class of porous materials with immense chemical tunability derived from their organic and inorganic building blocks. Presynthetic approaches have been used to construct tailor-made MOFs, but with a rather restricted functional group scope limited by the typical MOF solvothermal synthesis … WebFeb 12, 2010 · Our past work (as well as the work of others) has shown that MOFs with two mixed links can be prepared, whereas a recent report showed that four different … WebMay 2, 2013 · One MOF, many modifications: The postsynthetic transformation of C C double bonds is a versatile synthetic strategy for the introduction of functional groups in … hydromatic petker